In a galvanic cell, a spontaneous redox reaction occurs. however, the reactants are separated such that the transfer of electrons is forced to occur across a wire. the resulting cell potential is measured in volts (v) and is defined by the equation given below:

Lem 2 the data below are for the system ethyl propyl ether (1)-chloroform (2) at 0.5 bar. use the data to answer the following questions (all questions refer to p d 0: 5 bar). a) what are the boiling points of the pure components at 0.5 bar? b) a mixture with the overall composition z1 d 0: 1 is brought to 47.6ä±c, 0.5 bar. what is the phase? c) 100 mole of a mixture with z1 d 0: 1 (state a) is mixed with 22 mole of pure ethyl propyl ether vapor (state b). the mixing takes place at 47.6 ä±c, 0.5. bar. what is the phase of the resulting mixture (state c)? if the state is a v/l mixture report the number of moles and mole fractions in each phase. d) plot the txy graph and show states a, b and c. the graph must be done by computer and should be properly annotated. ethyl propyl ether (1) - chloroform (2) at 0.5 bar t ( ä±c) x1 y1 t ( ä±c) x1 y1 42.9 0.000 0.000 49.0 0.470 0.455 43.0 0.020 0.010 49.1 0.520 0.520 43.9 0.065 0.029 48.9 0.567 0.592 45.4 0.156 0.089 48.3 0.652 0.720 46.4 0.215 0.142 47.6 0.745 0.815 47.6 0.296 0.223 46.7 0.822 0.872 48.3 0.362 0.302 45.7 0.907 0.937 48.7 0.410 0.375 44.6 1.000

The scheme below is from a series of reactions that are part of a synthesis of vitamin a. answer the following questions with reference to this scheme. (i) what is "reagent a"? (ii) draw a step-by-step mechanism which explains the formation of compound c from compound b (iii) which reagents would you use to form compound e from compounds c and d (reagents b and c)? for each reagent suggested above in (ii) explain the role of the reagent in the reaction to (iv) form compound e. you may wish to do this by drawing a mechanism. 1. addition of reagent a но reagent a 2. н,о" thо oh нон-с compound a. compound b. compound c .ch-оh 1. reagent b "сно 2. reagent c сh oh compound e. compound d.

Consider this equilibrium: n29) + o2(g) + 2no(c).nitrogen gas and oxygen gas react when placed in a closed container. as the reaction proceeds towards equilibrium, what happens to the rate of thereverse reaction?