Chemistry, 28.01.2020 21:55 SAMANTHA8997

Excess magnesium reacts with 165.0 grams of hydrochloric acid in a single displacement reaction.
what volume of hydrogen gas is produced at stp?

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Answer from: taten1701

The volume of hydrogen gas produced will be approximately 50.7 liters under STP.

Explanation:

Relative atomic mass data from a modern periodic table:

H: 1.008;Cl: 35.45.

Magnesium is a reactive metal. It reacts with hydrochloric acid to produce

Hydrogen gas $\rm H_2$ , andMagnesium chloride, which is a salt.

The chemical equation will be something like

$\rm ?\;Mg\;(s) + ?\;HCl \;(aq)\to ?\;H_2 \;(g)+ [\text{Formula of the Salt}]$ ,

where the coefficients and the formula of the salt are to be found.

To determine the number of moles of $\rm H_2$ that will be produced, first find the formula of the salt, magnesium chloride.

Magnesium is a group 2 metal. The oxidation state of magnesium in compounds tends to be +2.

On the other hand, the charge on each chloride ion is -1. Each magnesium ion needs to pair up with two chloride ions for the charge to balance in the salt, magnesium chloride. The formula for the salt will be $\rm MgCl_2$ .

$\rm ?\;Mg\;(s) + ?\;HCl\;(aq) \to ?\;H_2 \;(g)+ ?\;MgCl_2\;(aq)$ .

Balance the equation. $\rm MgCl_2$ contains the largest number of atoms among all species in this reaction. Start by setting its coefficient to 1.

$\rm ?\;Mg\;(s) + ?\;HCl\;(aq) \to ?\;H_2 \;(g)+ {\bf 1\;MgCl_2}\;(aq)$ .

The number of $\rm Mg$ and $\rm Cl$ atoms shall be the same on both sides. Therefore

$\rm {\bf 1\;Mg}\;(s) + {\bf 2\;HCl}\;(aq) \to ?\;H_2 \;(g)+ {1\;\underset{\wedge}{Mg}\underset{\wedge}{Cl_2}}\;(aq)$ .

The number of $\rm H$ atoms shall also conserve. Hence the equation:

$\rm {1\;Mg}\;(s) + {2\;\underset{\wedge}{H}Cl}\;(aq) \to {\bf 1\;H_2 \;(g)}+ {1\;MgCl_2}\;(aq)$ .

How many moles of HCl are available?

$M(\rm HCl) = 1.008 + 35.45 = 36.458\;g\cdot mol^{-1}$ .

$\displaystyle n({\rm HCl}) = \frac{m(\text{HCl})}{M(\text{HCl})} = \rm \frac{165.0\;g}{36.458\;g\cdot mol^{-1}} = 4.52576\;mol$ .

How many moles of Hydrogen gas will be produced?

Refer to the balanced chemical equation, the coefficient in front of $\rm HCl$ is 2 while the coefficient in front of $\rm H_2$ is 1. In other words, it will take two moles of $\rm HCl$ to produce one mole of $\rm H_2$ . $\rm 4.52576\;mol$ of $\rm HCl$ will produce only one half as much $\rm H_2$ .

Alternatively, consider the ratio between the coefficient in front of $\rm H_2$ and $\rm HCl$ is:

$\displaystyle \frac{n(\text{H}_2)}{n(\text{HCl})} = \frac{1}{2}$ .

$\displaystyle n(\text{H}_2) = n(\text{HCl})\cdot \frac{n(\text{H}_2)}{n(\text{HCl})} = \frac{1}{2}\;n(\text{HCl}) = \rm \frac{1}{2}\times 4.52576\;mol = 2.26288\;mol$ .

What will be the volume of that many hydrogen gas?

One mole of an ideal gas occupies a volume of 22.4 liters under STP (where the pressure is 1 atm.) On certain textbook where STP is defined as $\rm 1.00\times 10^{5}\;Pa$ , that volume will be 22.7 liters.

$V(\text{H}_2) = \rm 2.26288\;mol\times 22.4\;L\cdot mol^{-1} = 50.69\; L$ , or

$V(\text{H}_2) = \rm 2.26288\;mol\times 22.7\;L\cdot mol^{-1} = 51.37\; L$ .

The value "165.0 grams" from the question comes with four significant figures. Keep more significant figures than that in calculations. Round the final result to four significant figures.

Answer from: Quest

assuming that your periodic table has eighteen columns, you should highlight the four elements in the third column from the left of the table.

explanation

neutral atoms of elements after calcium contain d electrons. the energy of d orbitals of a particular main shell lies between the energy of the s and p orbitals of the next main shell. for example, electrons in the $3d$ have energy higher than those in the $4 s$ orbital while lower than those of the $4 p$ orbital.

by the aufbau principle, electrons fill orbitals one at a time, starting from those of the lowest energy. the $4s$ orbital is therefore filled right after $3p$ orbitals and before $3 d$ orbitals.

potassium has electron configuration $[\text{ar}] 4 s^{1}$ and calcium $[\text{ar}] 4 s^{2}$ . the s orbital of a main shell holds a maximum of two electrons. the next element would thus have the electron configuration $[\text{ar}] 4 s^{2} \; 3d^{1}$ and satisfy the requirements.

a neutral atom of the element contains three electrons on top of the most recent noble gas element. it should thus be placed in the third column of the periodic table. both scandium and yttrium would satisfy the conditions. an aufbau diagram indicates that the 4f orbital is filled before the 5d. however, it appears that exceptions exists for both lanthanum and actinium. neutral atoms of the two d-block elements also demonstrate the $ns^{2} \; (n-1) p^{1}$ and should be highlighted as well.

Answer from: Quest

It will fall off and tip over.

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Excess magnesium reacts with 165.0 grams of hydrochloric acid in a single displacement reaction.

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