Complete the following single replacement reaction. if they don’t react, just write “nr” 1). fe(s) +cucl2(aq) 2). cu(s) + fecl2(aq) 3). k(s) + nibr2(aq) 4). ni(s) + kbr(aq) 5). zn(s) + ca(no3)2(aq) 6). ca(s) + zn(no3)2(aq)

Here we have to complete the given single replacement reactions.

The replacement reactions are-

1) Fe (s) + CuCl₂ (aq) → FeCl₂ (aq) + Cu (s)

2) Cu (s) + FeCl₂ (aq) → NA

3) K (s) + NiBr₂ (aq) → NA

4) Ni (s) + KBr (aq) → NiBr₂ (aq) + K (s)

5) Zn (s) + Ca(NO₃)₂ (aq) → Zn(NO₃)₂ (aq)  + Ca (s)

6) Ca (s) + Zn(NO₃)₂ (aq) → NA

The replacement reactions can be explained in light of the redox potential.

The standard reduction potential of the half cells involved in these reactions are:

Fe²⁺ + 2e → Fe (E° = -0.441V); Cu²⁺ + 2e → Cu (E° = 0.674V)

Ni²⁺ + 2e → Ni (E° = -0.23V); Zn²⁺ + 2e → Zn (E° = -0.763V)

We know the half cell reactions in which the standard reduction potentials are positive are allowed.

1) The reaction is possible as Cu²⁺/Cu and Fe/Fe²⁺ standard reduction potentials are positive.

2) The reaction is not possible as Cu/Cu²⁺ and Fe²⁺/Fe standard reduction potentials are negative.

3) The reaction is not possible as Ni²⁺/Ni standard reduction potential is negative.

4) The reaction is possible as Ni/Ni²⁺ standard reduction potential is positive.

5) The reaction is possible as Zn/Zn²⁺ standard reduction potential is positive.

6) The reaction is possible as Zn²⁺/Zn standard reduction potential is negative.

where is the following

explanation:

samuel de champlain. in 1608, king henry iv sponsored pierre dugua, sieur de mons and samuel de champlain as founders of the city of quebec with 28 men. this was the second permanent french settlement in the colony of canada.