Josh is doing an experiment with water. he starts with a plastic cup of water that has a mass of 12 grams. he places the cup in a sealed container and puts it in the freezer overnight. when he takes the container out of the freezer, he notices that the cup has cracked on its sides and the water is now frozen solid. which sentence best describes what josh discovers about the cup of frozen water? a) the mass of the cup of frozen water is 12 grams which means the mass did not change. b) the mass of the cup of frozen water is greater than 12 grams because it changed to a solid. c) the mass of the cup of frozen water is less than 12 grams because the frozen water is lighter than liquid water. d) the mass of the cup of frozen water is greater than 12 grams because the water expanded in the cup when it froze.

A) The mass of the cup of frozen water is 12 grams which means the mass did not change.

answer : the correct answer is 2) hno₃ and naoh .

arrhenius concept of acid and base :

acid :

according to arrhenius acid are those which release h⁺ or hydronium ion (h₃o⁺) in aqueous solution .

example : hcl +h₂o ↔ h₃o⁺ + cl⁻

hcl is giving h₃o⁺ ion in water , hence it is an arrhenius acid .

base :

according to arrhenius , bases are those which releases oh⁻ ions in aqueous solution .

example : koh (aq) ↔ k⁺ + oh⁻

since koh is producing oh⁻ ions hence , it is an arrhenius base .

checking the options :

1) ch₃oh and naoh :

ch₃oh is known as methanol , an organic compound , which is neutral compound . the dissociation of ch₃oh is negligible . it is very very weak acid (ka = 3.2 * 10 ⁻¹² ) .

naoh being ionic gives na⁺ and oh⁻ ions in aqueous solution as :

naoh ↔ na⁺ + oh⁻ . hence it is an arrhenius base

it can be concluded that ch₃oh and naoh is not arrhenius acid and base.

2) hno₃ and naoh :

hno₃ is an ionic compound which gives ions h⁺ and no₃⁻ ion in aqueous solution as:

hno₃ + h₂o ↔ h₃o⁺ + no₃⁻

since it is giving h⁺ ion . hno₃ is arrhenius acid .

naoh being ionic gives na⁺ and oh⁻ ions in aqueous solution as :

naoh ↔ na⁺ + oh⁻

. hence it is an arrhenius base .

it can be said that hno₃ and naoh are arrhenius acid and base.

3) ch₃oh and hcl

as discussed ch₃oh is neutral compound .

while hcl in aqueous solution dissociates to give h⁺ and cl⁻ ions as :

hcl + h₂o→ h₃o⁺ + cl⁻ . so hcl is arrhenius acid .

hence , ch₃oh and hcl are not arrhenius acid and base.

4) hno₃ and hcl :

hno₃ as discussed gives h⁺ in aqueous solution , while hcl also gives h⁺ in aqueous solution .

hence both hno₃ and hcl are arrhenius acid they are not acid and base .

so the arrhenius acid and base are 2) hno₃ and naoh.